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Instructor Name

Anuradha Mukherjee

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Course Description

1.  Chemistry behind electrophilic addition of alkenes and alkynes

2. Details of various electrophilic addition like hydration, halogenation, halohydration

3, Discussion on Markovnikov's and Anti-Markovnikov's rule 

4. Ozonolysis of alkene: Electrophilic addition proceeds via oxidative cleavage of double bond

5. Ozonolysis: Oxidative vs reductive work up

6. Synthesis of vicinal alcohols from alkenes

7. Reactions of alkene using cold alkaline KMnO4 vs hot alkaline KMnO4

8. Electrophilic addition of alkynes: Halogenation using Br2/CCl4 and hydrohalogenation using HCl/HBr

6. Oxymercuration demercuration and hydroboration -oxidation: Alkenes vs alkyne

7. Ozonolysis of alkynes

Course Outcomes

This mechanism will build a foundation to understand the reactions of alkenes and alkynes. It will also strengthen the concept on synthesis of alkyl halides and alcohols from alkenes using different types of electrophilic addition

Ozonolysis reaction also emphasize on synthesis of carbonyl compounds and carboxylic acids.

Course Curriculum

1. Electrophilic Addition : Reaction mechanism Part 2

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Electrophilic Addition: Reaction Mechanism: Part 2

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